高分辨电感耦合等离子体磁质谱法测定含铜不锈钢中痕量磷

作者通过试验,用电感耦合等离子体磁质谱(HR-ICP-MS)测定含铜不锈钢中磷含量时,采用高分辨率模式,选择分辨率为4000,在此条件下磷峰可与干扰双原子分子或离子的峰分开。又通过以含铁基的磷标准溶液优化了气体流量和离子透镜的参数,使磷的信号值提高至3×105cps。而加入45Sc作为内标元素又可显著提高测定的稳定性。分别用不锈钢样品和纯铁粉作基体,加入标准溶液制作标准曲线。结果表明:两种方法的线性均较好,分别测得实际样品的结果及其相对标准偏差也基本一致。但两种方法的检出限(3s)不同,前者为1.0μg·g^-1,后者为0.18μg·g^-1。所提出方法的样品处理过程如下:称取样品0.10g置于消解罐中,加入盐酸溶液2mL及硝酸溶液1mL,待剧烈反应缓解时,将消解罐加盖并置于微波消解仪中,于100℃消解10min,升温至200℃继续消解20min。冷却后将溶液转移至100 mL石英容量瓶中,加入0.2mg·L^-1钪内标溶液1mL,加水至刻度,摇匀。此溶液在仪器工作条件下进行HR-ICP-MS测定。对含磷51μg·g^-1的含铜不锈钢,按本方法测定所得结果的相对标准偏差(n=10)小于4%。应用本方法分析了7种标准物质或已知样品(包括低合金钢、含铜不锈钢、高温合金),并同时用ICP-AES进行校对分析。结果表明,本方法与ICP-AES的测定结果基本一致。但本方法的结果与标准物质的认定值更接近,而且对低含量磷(9μg·g^-1)也可很好测定。     

Experimental investigation of circular free-surface jet impingement quenching: Transient hydrodynamics and heat transfer

An experimental study of heat transfer during quenching of a cylindrical stainless steel test specimen has been performed. A subcooled water jet is directed onto the upward facing flat face of the cylinder. The test specimen is heated to an initial temperature slightly above 900 °C and then quenched. The resulting boiling curves and heat transfer distributions are presented for impingement velocities of 2.85 and 6.4 m/s (Re = 7900 and 18,900). High-speed imaging shows that three distinct regions on the quenched surface can be identified: an expanding circular wetted region surrounding the impinging point, annular transition zone just outside the wetting front, and a unwetted region outside this zone. The free-surface of the liquid in the wetted region is smooth in the nucleate and transition boiling regimes. The annular transition zone or the wetting front region outside the wetted region is characterized by a highly disturbed liquid-gas interface, which can be attributed to intense vapor generation. At the outer edge of the transition zone, the liquid is deflected away from the surface. The velocity of the wetting front significantly increases with the jet impact velocity, which indicates that the wetting front position is governed by the ability of the flowing liquid to transport the bubbles radially outwards from the wetted region.     

杆弹侵彻钢纤维混凝土实验研究

采用DOP实验方法,进行了35CrMnSiA杆弹对不同钢纤维体积含量的钢纤维混凝土的侵彻实验.分别研究了杆弹着速和钢纤维体积含量对钢纤维混凝土杭侵彻性能的影响.实验表明,随着弹速增加,不同钢纤维含量的钢纤维混凝土侵彻深度都会增加,但钢纤维混凝土中弹体便深增加较素混凝土缓慢;而钢纤维能增强混凝土的抗侵彻性能,且随钢纤维体...     

激光毛化轧辊技术的特色与进展

轧辊激光毛化技术的用途是什么? 什么样的轧辊需要毛化处理? 激光毛化轧辊技术 的优势是什么? 还存在什么不足? 激光毛化处理为什么能够延长轧辊的寿命? 激光毛化轧辊 改善了所轧钢板的哪些性能? 其机制是什么? 针对轧辊激光毛化技术的这几个基本问题 进行了讨论和释疑, 并指出了下一步的改进方向.     

16Mn钢在不同条件下的疲劳行为研究

对截面为3 mm×3mm的16Mn钢试件在空气和3.5%NaCl溶液中分别进行疲劳试验,获得了S-N曲线,并对疲劳试样表面和断口形貌进行了观察.结果表明:与空气相比,3.5%NaCl腐蚀溶液使16Mn钢的疲劳强度显著降低;在空气中疲劳试样只有一个萌生于试样表面基体的裂纹源,而在3.5%NaCl溶液中一般有多个裂纹源,而...     

爆炸复合1Cr13Mo/45钢连铸辊工艺

鉴于目前连铸辊制造工艺存在的不足,以爆炸复合法制造1Cr13Mo/45钢复合轧辊,并以爆炸复合工艺为研究对象,采用超声波探伤和金相观察等方法,研究药厚和间隙大小对复合界面波形的影响.结果表明:药厚一定的情况下,间隙对复合轧辊界面波形的影响较大;而在间隙一定的情况下,药厚对复合轧辊界面波形的影响不明显.通过实验,获得了该...     

半穿甲弹设计及穿甲实验研究

为提高半穿甲弹的穿甲能力,设计了一种贫铀半穿甲实验弹。对实验弹的飞行稳定性进行了理论分析及数值模拟,两种方法计算得到的实验弹稳定储备量基本吻合,且能够满足实验弹的飞行稳定性要求。采用100mm滑膛炮,开展了贫铀半穿甲弹侵彻装甲靶板实验。实验结果表明,实验弹飞行稳定,与理论分析及数值模拟结果一致;实验弹在25°倾角下贯穿三层20mm厚GY4装甲钢,且回收到的弹体基本完好。通过对实验后的实验弹和靶板进行分析,认为贫铀半穿甲弹的穿甲能力较强。     

激光硬化9SiCr表面土壤磨损研究

在壤土、沙土和黏土3种土壤中对激光处理的9SiCr材料进行磨损试验,考察了激光硬化工艺参数对9SiCr 旋耕刀基体显微硬度的影响,获得9SiCr 旋耕刀基体激光硬化处理的最佳工艺参数。结果表明：在激光功率为1 200W、扫描速度为14mm/s和激光功率1500W、扫描速度16mm/s的条件下,磨损率较小。激光处理表面在3种土壤条件下进行了耐磨性比较,沙土对试件的磨损率影响最小。9SiCr经过激光处理其表面耐磨性比一般淬火表面的耐磨性提高约5倍。9SiCr表面磨损形式主要是磨粒磨损。激光处理9SiCr表面提高了表面硬化层的硬度,从而提高了材料的耐磨性,增加了9SiCr的使用寿命。     

Effect of surface nanocrystallization induced by fast multiple rotation rolling on hardness and corrosion behavior of 316L stainless steel

A nanostructured layer was fabricated by using fast multiple rotation rolling (FMRR) on the surface of 316L stainless steel. The microstructure in the surface was characterized by transmission electron microscopy and X-ray diffraction. The effects of FMRR on the microhardness, surface roughness and corrosion behavior of the stainless steel were investigated by microhardness measurements, surface roughness measurements, potentiodynamic polarization curves and pitting corrosion tests. The surface morphologies of pitting corrosion specimens were characterized by scanning electron microscopy. The results show that FMRR can cause surface nanocrystallization with the grain size ranges from 6 to 24 nm in the top surface layer of the sample. The microhardness of FMRR specimen in the top surface layer remarkably increases from 190 to 530 HV. However, the surface roughness slightly rises after FMRR treatment. The potentiodynamic polarization curves and pitting corrosion tests indicated that the FMRR treated 316L stainless steel with a surface nanocrystallized layer reduced the corrosion resistance in a 3.5% NaCl solution and enhanced the pitting corrosion rate in a FeCl₃ solution. Possible reasons leading to the decrease in corrosion resistance were discussed.     

Coating of Cr-V ledeburitic steel with CrN containing a small addition of Ag

Samples made from Vanadis 6 PM ledeburitic tool steel were surface machined, ground, and mirror polished. They were heat treated and coated with CrN with and without Ag addition by reactive magnetron sputtering. The CrN film grew in a typically columnar manner. A small addition of 3% Ag did not lead to alterations in the growth mechanism. The hardness of the CrN coating was 16.79 ± 1.49 GPa compared to 15.97 ± 1.44 GPa for the coating with Ag addition. The Ag addition in the CrN improved adhesion of the coating, which can be attributed to the capability of CrAgN coating to accommodate higher deformation energy before failure. The CrAgN coating exhibited superior tribological properties at intermediate temperatures. Compared to pure CrN the friction coefficient is lowered to 70-75% when measured at 400 and 500 °C, respectively. This is reflected in a reduction in the volume wear, which was found to be three times lower for the coating containing Ag. Flexural strength decreased slightly for the CrN- or CrAgN-coated material compared to uncoated steel. However, as the decrease in flexural strength is very weak there is practically no risk of significant embrittlement of the investigated material due to the CrN coating with or without Ag addition.